This item cannot be synchronised yet, because your expense synchronisation settings don’t allow it. For example, your settings may state that an expense must be approved before it is synchronised, or that the transaction must be final. For more information, see this help article.
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To check your current settings in the web app, go to Settings > Integrations and select your accounting provider, and then check the Expense Sync Settings section. If you elect to change your settings (depending on your business requirements), make sure that you click Save at the bottom of the page. You can then retry synchronisation by clicking the Sync button on the expense.

This item cannot be synchronised yet as it has not yet been approved. Once its approved it will be synced immediately.